Synthesis and structure of certain O-pyrimidinyl-oximes of 2,2-dimethyltetrahydro-4-pyranone
Abstract
By reactions of substituted chloropyrimidines with the sodium salt of 2,2-dimethyltetrahydro-4-pyranone oxime, pyrimidinyloximes of 2,2-dimethyltetrahydro-4-pyranone have been obtained. On the basis of X-ray diffraction studies of the O-(2,4-dimethyl-6-pyrimidinyl)oxime of 2,2-dimethyltetrahydro-4-pyranone, it has been shown that the oxygen atoms of the oxime group and the carbon in position 2 of the pyran ring are in the anti position relative to the double bond of the oxime.
How to Cite
Danagulyan, G. G.; Karapetyan, A. A.; Zalinyan, M. G.; Balasanyan, N. G.; Safaryan, A. A.; Mailyan, N. Sh. Chem. Heterocycl. Compd. 1997, 33, 838. [Khim. Geterotsikl. Soedin. 1997, 957.]
For this article in the English edition, see DOI https://doi.org/10.1007/BF02253036