Heterocyclic analogs of pleiadiene. 63. Synthesis and crystal structure of 1-aminoperimidines

Authors

  • А. Ф. Пожарский Rostov State University, Rostov-on-Don 344090
  • О. В. Крышталюк Rostov State University, Rostov-on-Don 344090
  • Г. Г. Александров Rostov State University, Rostov-on-Don 344090
  • В. B. Кузьменко Rostov State University, Rostov-on-Don 344090

Abstract

By action of O-picrylhydroxylamine on perimidine and 2-methylperimidine, we have synthesized their 1-amino derivatives. An X-ray diffraction investigated of 1-aminoperimidine showed that the amino group in them is found in a pyramidal configuration with the axis of the unshared electron pair lying in the plane of the heterocyclic ring, oriented toward the μ-carbon atom.

How to Cite
Pozharskii, A. F.; Kryshtalyuk, O. V.; Aleksandrov, G. G.; Kuz'menko, V. V. Chem. Heterocycl. Compd. 1995, 31, 92. [Khim. Geterotsikl. Soedin. 1995, 103.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171300

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Published

1995-01-25

Issue

No. 1 (1995)

Section

Original Papers