EFFECTIVE SYNTHESIS OF <i>N</i>-ARYL-SUBSTITUTED 1,5,3-DITHIAZEPINANES AND 1,5,3-DITHIAZOCINANES

Authors

  • Е. Б. Рахимова Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
  • И. В. Васильева Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
  • Л. М. Халилов Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
  • А. Г. Ибрагимов Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
  • У. М. Джемилев Institute of Petrochemistry and Catalysis, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1125

Keywords:

arylamines, N-aryl-1, 5, 3-dithiazepinanes, 3-dithiazocinanes, N-tert-butyl-1, 3-dithiazepinane, 1-oxa-3, 6-dithiacycloheptane, 7-dithiacyclooctane, catalysis, recyclization, transamination

Abstract

Selective methods were developed for the synthesis of N-aryl-1,5,3-dithiazepinanes and N-aryl-1,5,3-dithiazocinanes by transamination of N-tert-butyl-1,5,3-dithiazepinane or recyclization of 1-oxa-3,6-dithiacycloheptane and 1-oxa-3,7-dithiacyclooctane by the action of aniline derivatives in the presence of Sm(NO3)3·6H2O catalyst.

Authors: E. B. Rakhimova, I. V. Vasil'yeva, L. M. Khalilov, A. G. Ibragimov, and U. M. Dzhemilev.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (7), pp 1050-1057

http://link.springer.com/article/10.1007/s10593-012-1098-8

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Published

2013-11-05

Issue

No. 7 (2012)

Section

Original Papers