HETEROCYCLIZATION OF CYCLOALKENES WITH DI(2-PYRIDYL) DISELENIDE IN THE PRESENCE OF ANTIMONY PENTACHLORIDE

Authors

  • А. В. Борисов R. E. Alekseev State Technical University
  • Ж. В. Мацулевич R. E. Alekseev State Technical University
  • В. К. Османов R. E. Alekseev State Technical University
  • Г. Н. Борисова R. E. Alekseev State Technical University
  • Г. З. Мамедова Baku State University
  • А. М. Магеррамов Baku State University
  • В. Н. Хрусталев A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1178

Keywords:

alkenes, antimony pentachloride, di(2-pyridyl) diselenide, heterocyclization

Abstract

Cycloalkenes react with di(2-pyridyl) diselenide in the presence of antimony pentachloride with the formation of products of the selenenylating electrophile cycloaddition at the multiple bond. The final products of heterocyclization, chloroantimonates(III) of 2,3-dihydro[1,3]selenazolo[3,2-a]pyridinium derivatives were isolated.

Authors: A.V. Borisov, Zh. V. Matsulevich, V. K. Osmanov, G. N. Borisova, G. Z. Mammadova, A. M. Maharramov, and V. N. Khrustalev.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (6), pp 963-968

http://link.springer.com/article/10.1007/s10593-012-1084-1

Published

2013-11-19

Issue

Section

Original Papers