SYNTHESIS OF HEXAHYDRO[1,4]DIAZOCINO[7,8,1-<i>jk</i>]CARBAZOLES AND 1-METHOXY-9-(β-VINYLETHYLAMINO)ETHYLCARBAZOLES

Authors

  • Л. Г. Воскресенский People's Friendship University of Russia
  • В. Г. Граник People's Friendship University of Russia
  • Т. Н. Борисова People's Friendship University of Russia
  • А. А. Титов People's Friendship University of Russia
  • Е. И. Гришина People's Friendship University of Russia
  • Е. А. Сорокина People's Friendship University of Russia
  • А. В. Варламов People's Friendship University of Russia

DOI:

https://doi.org/10.1007/1215

Keywords:

hexahydrodiazocinocarbazoles, 1-methoxy-9-(β-vinylethylamino)ethylcarbazoles, pyrazine ring cleavage domino reaction, pyrazine ring extension domino reaction

Abstract

3-Ethylhexahydropyrazino[3,2,1-jk]carbazole is converted into hexahydro[1,4]diazocino[7,8,1-jk]carbazoles by the action of methyl propiolate and acetylacetylene in acetonitrile and into 1-methoxy-9-(β-vinylethylamino)ethylcarbazoles by the action of acetylenedicarboxylic ester and methyl propiolate in methanol. 3-Benzyl-substituted pyrazinocarbazole does not react with alkynes.

Authors: L. G. Voskressensky, V. G. Granik, T. N. Borisova, A. A. Titov, E. I. Grishina, E. A. Sorokina, and A. V. Varlamov.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (4), pp 620-624

http://link.springer.com/article/10.1007/s10593-012-1035-x

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Published

2013-11-21

Issue

No. 4 (2012)

Section

Original Papers