REDUCTION OF 3-(CARBOXYARYL)ISOCOUMARINS WITH SODIUM BOROHYDRIDE

Authors

  • В. В. Ищенко Kyiv Taras Shevchenko National University
  • Н. М. Воевода Kyiv Taras Shevchenko National University
  • О. В. Шаблыкина Kyiv Taras Shevchenko National University
  • А. В. Туров Kyiv Taras Shevchenko National University
  • В. П. Хиля Kyiv Taras Shevchenko National University

DOI:

https://doi.org/10.1007/1365

Keywords:

amides, 3-aryl-3, 4-dihydroisocoumarins, 3-arylisocoumarins, 3-(2-carboxybenzyl)-2-benzofuran-1(3H)-ones, carboxyl group, esters

Abstract

Reduction of 3-(carboxyaryl)isocoumarins with sodium borohydride proceeds with formation of corresponding 3-carboxyaryl-3,4-dihydroisocoumarins or isomeric dihydrophthalides, 3-(2-carboxybenzyl)-2-benzofuran-1(3H)-ones. Derivatives at the carboxyl group of 3-carboxyaryl-3,4-dihydroisocoumarins and 3-(2-carboxybenzyl)-2-benzofuran-1(3H)-ones have been obtained.

Authors: V. V. Ishchenko, N. M. Voevoda, O. V. Shablykina, A. V. Turov, and V. P. Khilya.

English translation in Chemistry of Heterocyclic Compounds, 2011, 47 (10), pp 1212-1224

http://link.springer.com/article/10.1007/s10593-012-0896-3

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Published

2013-12-13

Issue

No. 10 (2011)

Section

Original Papers