ELECTRONIC SPECTRA AND STRUCTURE OF METHYL DERIVATIVES OF 4-NITROPYRIDINE N-OXIDE

Авторы

  • L. Wasylina Editorial Office "Chemistry of Heterocyclic Compounds"
  • A. Puszko Department of Organic Chemistry, University of Economics, Wroclaw

DOI:

https://doi.org/10.1007/238

Ключевые слова:

methyl-4-nitropyridine N-oxides, UV spectra, INDO calculations

Аннотация

The UV spectra of seven methyl derivatives of 4-nitropyridine N-oxide in ethanol have been examined. The electronic spectra were calculated by a modified INDO method. Transition energies, intensities and assignments were compared with UV spectra. Spectroscopic manifestations of intramolecular interaction indicate that methyl groups modify the electronic interaction between the N-oxide and NO2 groups mainly through a steric strain.

Also published in Chemistry of Heterocyclic Compounds, 2000, 36 (6), pp 686-692

http://link.springer.com/article/10.1007/BF02297677

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Опубликован

2013-02-04

Выпуск

Раздел

Оригинальные статьи