SYNTHESIS OF PHOTOCHROMIC BISFULGIMIDES BY THE CONDENSATION OF (3<i>Z</i>)-3-[1-(2,5-DIMETHYL-3-THIENYL)ETHYLIDENE]-4-ISOPROPYLIDENE-2,5-FURANDIONE WITH AROMATIC DIAMINES

Authors

  • С. И. Луйксаар N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • М. М. Краюшкин N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Ю. А. Пьянков Photochemistry Center, Russian Academy of Sciences
  • В. А. Барачевский Photochemistry Center, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/3071

Keywords:

3-acetyl-2, 5-dimethylthiophene, fulgides, fulgimides, Stobbe condensation, photochromism

Abstract

The first representatives of thiophene derivatives with two fulgimide fragments in one molecule have been obtained by the condensation of (3Z)-3-[1-(2,5-dimethyl-3-thienyl)ethylidene]-4-isopropylidene-2,5-furandione with aromatic diamines. The photochromic properties of the obtained compounds have been investigated and the effect of a spacer, linking the two fulgimide fragments, on the reaction rates of photocoloration and photodecoloration of these compounds has been studied.

How to Cite
Luyksaar, S. I.; Krayushkin, M. M.; Pyankov, Yu. A.; Barachevsky, V. A. Chem. Heterocycl. Compd. 2010, 46, 822. [Khim. Geterotsikl. Soedin. 2010, 1019.]

For this article in the English edition see DOI 10.1007/s10593-010-0589-8

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Published

2016-02-22

Issue

No. 7 (2010)

Section

Original Papers