ANYSIL-, AMINOPHENYL-, AND NAPHTHYLMETHYLSILATRANES REVISITED

Authors

  • Yu Wang UMR 6226 ISCR, University of Rennes I, 35042 Rennes
  • Vitalijs Romanovs Latvian Institute of Organic Synthesis, 21 Aizkraukles St., Riga LV-1006
  • Jana Spura Latvian Institute of Organic Synthesis, 21 Aizkraukles St., Riga LV-1006
  • Lubova Ignatovica Latvian Institute of Organic Synthesis, 21 Aizkraukles St., Riga LV-1006
  • Thierry Roisnel UMR 6226 ISCR, University of Rennes I, 35042 Rennes
  • Viatcheslav Jouikov UMR 6226 ISCR, University of Rennes I, 35042 Rennes

DOI:

https://doi.org/10.1007/3318

Keywords:

silatranes, DFT calculations, N–Si dative bond, , synthesis, X-ray structure

Abstract

Three Si-substituted silatranes were synthesized in order to rectify their structure with particular attention to the length of the N–Si intramolecular dative bond. DFT calculations of potential energy profile as a function of the N–Si distance and the structure of HOMO were considered. The latter was found to vary its localization depending on the electron-donating properties of the substituent and the N–Si distance.

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Published

2016-08-29

Issue

Vol. 52 No. 8 (2016)

Section

Original Papers