SYNTHESIS AND HALOCYCLIZATION OF 4-METHYLQUINOLIN-2(1<i>H</i>)-ONE <i>N</i>- AND <i>O</i>-METHALLYL DERIVATIVES

Authors

  • Дмитрий Г. Ким South Ural State University (National Research University)
  • Евгения А. Вершинина South Ural State University (National Research University)
  • Ирина Г. Овчинникова I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
  • Павел А. Слепухин I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
  • Марина А. Ежикова I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
  • Михаил И. Кодесс I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/4689

Keywords:

dihydrooxazolo[3, 2-а]quinolinium halides, methallyl chloride, 1-methallyl-4-methylquinolin-2(1Н)-one, 2-methallyloxy-4-methylquinoline, 4-methylquinolin-2(1Н)-one, halocyclization

Abstract

The alkylation of 4-methylquinolin-2(1Н)-one with methallyl chloride gave a regioisomer mixture containing 1-methallyl-4-methylquinolin-2(1Н)-one and 2-methallyloxy-4-methylquinoline, which reacted with iodine and bromine and formed dihydrooxazolo[3,2-а]-quinolinium systems.

Authors: Dmitry G. Kim, Evgeniya A. Vershinina, Irina G. Ovchinnikova,
Pavel A. Slepukhin, Marina A. Ezhikova, Mikhail I. Kodess

Author Biographies

Дмитрий Г. Ким, South Ural State University (National Research University)

кафедра теоретической и прикладной химии

д.х.н., профессор

Евгения А. Вершинина, South Ural State University (National Research University)

кафедра теоретической и прикладной химии

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Published

2018-11-12

Issue

Vol. 54 No. 10 (2018)

Section

Original Papers