SYNTHESIS OF FLUORINATED DIPYRAZOLYL SULFONES FROM BIS(2-FLUORO-2-POLYFLUOROALKYLALKENYL) SULFONES AND DIAZOMETHANE
Authors
Ярослав С. Бородкин
Institute of Organic Chemistry, National Academy of Sciences of Ukraine,
5 Murmanska St., Kyiv 02660, Ukraine
Эдуард Б. Русанов
Institute of Organic Chemistry, National Academy of Sciences of Ukraine,
5 Murmanska St., Kyiv 02660, Ukraine
Александр И. Хижан
Enamine Ltd.,
78 Chervonotkatska St., Kyiv 02094, Ukraine
L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine
50 Kharkiv Shosse, Kyiv 02160, Ukraine
Юрий Г. Шермолович
Institute of Organic Chemistry, National Academy of Sciences of Ukraine,
5 Murmanska St., Kyiv 02660, Ukraine
The reactions of diazomethane with bis(2-fluoro-2-polyfluoroalkylalkenyl) sulfones are accompanied by dehydrofluorination and lead to the formation of new dipyrazolyl sulfones containing polyfluoroalkyl substituents at position 4 of the pyrazole ring. The structure of four new sulfones was confirmed by X-ray diffraction analysis.
