NEW DATA ON THE REACTIVITY OF 2-UNSUBSTITUTED 3-HALOCHROMONES

Authors

  • Вячеслав Я. Сосновских Institute of Natural Sciences and Mathematics, Ural Federal University named after the first President of Russia B. N. Yeltsin, 51 Lenina Ave., Yekaterinburg 620000, Russia

DOI:

https://doi.org/10.1007/5445

Keywords:

3-halochromone, heterocyclization, bisnucleophile, cycloaddition, metal-catalyzed reaction, mononucleophile.

Abstract

Generalized and systematized information is provided on the chemical properties of 3-halochromones, which can be viewed as geminally activated push-pull haloalkenes. The main focus of this review article is on nucleophilic reactions that can proceed in three different directions with both mono- and bisnucleophiles and can be accompanied by pyrone ring cleavage or preservation. In addition, cycloaddition reactions and metal-catalyzed reactions involving 3-halochromones are described. A total of 56 references are provided.

Author Biography

Вячеслав Я. Сосновских, Institute of Natural Sciences and Mathematics, Ural Federal University named after the first President of Russia B. N. Yeltsin, 51 Lenina Ave., Yekaterinburg 620000, Russia

Зав. кафедрой органической химии м высокомолекулярных соединений Института естественных наук и математики Уральского федерального университета

Published

2020-04-01

Issue

Section

Review Articles