MAGNESIUM ACETATE – AN EFFECTIVE ELECTROPHILIC ACTIVATOR OF THE CARBONYL GROUP IN TRANSESTERIFICATION OF DIALKYLAZIRIDINE DICARBOXYLATES

Authors

  • Ангелина В. Казакова Institute of Chemistry, Saint Petersburg State University, 7/9 University Embankment, Saint Petersburg 199034
  • Дмитрий В. Андросов Institute of Chemistry, Saint Petersburg State University, 7/9 University Embankment, Saint Petersburg 199034
  • Александр С. Конев Institute of Chemistry, Saint Petersburg State University, 7/9 University Embankment, Saint Petersburg 199034
  • Александр Ф. Хлебников Institute of Chemistry, Saint Petersburg State University, 7/9 University Embankment, Saint Petersburg 199034

DOI:

https://doi.org/10.1007/5752

Keywords:

aziridines, fullerenes, 1, 3-dipolar cycloaddition, electrophilic activation, stereodirected synthesis, transesterification

Abstract

A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.

Authors: Angelina V. Kazakova, Dmitriy V. Androsov, Alexander S. Konev*, Alexander F. Khlebnikov

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Published

2020-08-18

Issue

Vol. 56 No. 7 (2020): Synthesis and transformations of heterocycles under electrophilic conditions

Section

Original Papers