SYNTHESIS OF DIHYDROBENZOTHIAZEPINES BASED ON 1-ACYL-2-HETERYL-1-NITROETHENES

Authors

  • Руслан И. Байчурин Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia
  • Сергей В. Макаренко Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia

DOI:

https://doi.org/10.1007/6335

Keywords:

gem-acylnitroethene, 2-aminobenzothiol, 1, 5-benzothiazepine, 2, 3-dihydro-1, enone, nitroethene.

Abstract

The reactions of thiophene- and N-benzylindole-containing gem-acetylnitroethenes with 2-aminobenzothiol lead to the formation of 4-methyl-3-nitro-2,3-dihydro-1,5-benzothiazepines. At the same time, only S-adducts were formed in the reactions of gem-benzoylnitroethenes containing a thiophene, furan, or N-benzylindole substituent with 2-aminobenzothiol.

Author Biography

Сергей В. Макаренко, Herzen State Pedagogical University of Russia, 48 Moyka River Embankment, Saint Petersburg 191186, Russia

Д.х.н., доцент.

Факультет химии РГПУ им. А.И. Герцена - декан

Кафедра органической химии РГПУ им. А.И.Герцена - заведующий кафедрой.

ЦКП при факультете химии РГПУ им. А.И.Герцена - директор

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Published

2021-09-22

Issue

Vol. 57 No. 9 (2021)

Section

Original Papers