SYNTHESIS AND SOME CHEMICAL CONVERSIONS OF ACETYLENIC DERIVATIVES OF 1,4-DIOXANE

Authors

  • М. Г. Велиев Institute of Polymeric Materials, National Academy of Sciences of Azerbaijan, Sumgait Az5004
  • М. И. Шатирова Institute of Polymeric Materials, National Academy of Sciences of Azerbaijan, Sumgait Az5004
  • О. В. Аскеров Institute of Polymeric Materials, National Academy of Sciences of Azerbaijan, Sumgait Az5004

DOI:

https://doi.org/10.1007/6554

Keywords:

acetylenic alcohols, diacetylenic derivatives, 1, 4-dioxanes, ethylene bromohydrin, aminomethylation, diene condensation, hydrosilylation

Abstract

The possibility has been shown of synthesizing acetylenic derivatives of 1,4-dioxane in high yield by the interaction of glycidyl ethers of acetylenic alcohols with ethylene bromohydrin in the presence of boron trifluoride etherate. Dehydrobromination of the corresponding bromohydrin was then carried out in the presence  of  metallic sodium in absolute diethyl ether. Acetylenic derivatives of 1,4-dioxane enter into hydrosilylation, aminomethylation,  and  diene  condensation reactions with the formation of new derivatives of 1,4-dioxane.

How to Cite
Veliev, M. G.; Shatirova, M. I.; Askerov, O. V. Chem. Heterocycl. Compd. 2009, 45, 1190. [Khim. Geterotsikl. Soedin. 2009, 1485.]

For this article in the English edition see DOI 10.1007/s10593-010-0406-4

 

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Published

2022-02-09

Issue

No. 10 (2009)

Section

Original Papers