THE REACTIONS OF ARYLAZASYDNONES WITH S- AND O-NUCLEOPHILES

Authors

  • Александр В. Корманов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Татьяна К. Шкинева N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Игорь Л. Далингер N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

DOI:

https://doi.org/10.1007/7461

Keywords:

азасиднон, нитроарилазасиднон, 1, 2, 3, 4-оксатриазолий-5-олат, мезоионные соединения, нуклеофильное замещение, полиазотные гетероциклы.

Abstract

A series of 3-arylazasydnone derivatives containing a chlorine atom and nitro group at various phenyl ring locations were functionalized by a method developed on the basis of reactions with different S- and O-nucleophiles. In all cases, an SNAr reaction was shown to occur where the leaving group could be either a halogen or azasydnone moiety, depending on their mutual position.

 

Author Biographies

Александр В. Корманов, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

научный сотрудник, к.х.н.

Татьяна К. Шкинева, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

старший научный сотрудник, к.х.н.

Игорь Л. Далингер, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

ведущий научный сотрудник, д.х.н.

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Published

2023-06-01

Issue

Vol. 59 No. 4/5 (2023)

Section

Original Papers