SYNTHESIS AND X-RAY STRUCTURAL INVESTIGATION OF ZINC 2-METHYL-8-SELANYLQUINOLINATE. COMPARATIVE CRYSTALLOGRAPHIC ANALYSIS OF THE ZINC 8-SULFANYL-, 8-SELANYL-, AND 2-METHYL-8-SELANYLQUINOLINATE MOLECULES

Authors

  • Л. Печ Inorganic Chemistry Institute ot the Riga Technical University, Salaspils LV-2169
  • С. Беляков Latvian Institute for Organic Synthesis, Riga LV-1006
  • Я. Ашакс Inorganic Chemistry Institute ot the Riga Technical University, Salaspils LV-2169
  • Э. Силинь Inorganic Chemistry Institute ot the Riga Technical University, Salaspils LV-2169
  • Д. Зарума Inorganic Chemistry Institute ot the Riga Technical University, Salaspils LV-2169

DOI:

https://doi.org/10.1007/7709

Keywords:

intramolecular zinc compounds, zinc 8-sulfanyl-, 8-selenol-, and 2-methyl-8-selanylquinolinates, molecular structure, X-ray analysis

Abstract

Zinc 2-methyl-8-selanylquinolinate Zn[C9H5(Me)NSe]2 has been synthesized and its structure proved by X-ray analysis. The effect of different ligand atoms (Se or S) and a methyl group in position 2 of the ligand on the geometry of the coordinated zinc atom polyhedron has been studied for zinc 8-sulfanyl-, 8-selanyl-, and 2-methyl-8-selanylquinolinate.

How to Cite
Pech, L.; Belyakov, S.; Ashaks, Ya.; Silina, E.; Zaruma, D.  Chem. Heterocycl. Compd. 2007, 43, 106. [Khim. Geterotsikl. Soedin. 2007, 123.]

For this article in the English edition see DOI 10.1007/s10593-007-0016-y


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Published

2023-04-06

Issue

No. 1 (2007)

Section

Original Papers