SYNTHESIS AND PROPERTIES OF β-OXO SULFIDES OF THE DIOXOTHIOLANE SERIES

Authors

  • С. Н. Гайдамака Institute of Biochemistry and Petrochemistry, National Academy of Sciences of Ukraine, Kiev 02094
  • О. А. Шанталий Institute of Biochemistry and Petrochemistry, National Academy of Sciences of Ukraine, Kiev 02094
  • И. А. Ральчук Institute of Biochemistry and Petrochemistry, National Academy of Sciences of Ukraine, Kiev 02094

DOI:

https://doi.org/10.1007/8236

Keywords:

β-hydroxy sulfides, β-oxo sulfides, five-membered cyclic sulfones, selective oxidation, chemical properties

Abstract

It was shown that the hydroxy group in  β-hydroxy sulfides of the dioxothiolane series can be oxidized selectively to a carbonyl group in the presence of a sulfide group. A sequence of transformations leading to the final β-oxo sulfides was proposed and was confirmed experimentally. A new original method was developed for the production of β-oxo sulfides. Some characteristics of the synthesized compounds were studied.

How to Cite
Gaydamaka, S. N.; Shantaliy, O. A.; Raltshuk, I. A.  Chem. Heterocycl. Compd. 2005, 41, 820. [Khim. Geterotsikl. Soedin. 2005, 974.]

For this article in the English edition, see DOI 10.1007/s10593-005-0232-2


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Published

2023-10-31

Issue

No. 7 (2005)

Section

Original Papers