DIOXIMES OF 1,3-DIKETONES IN THE TROFIMOV REACTION: NEW 3-SUBSTITUTED PYRROLES

Authors

  • А. Б. Зайцев A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • E. Ю. Шмидт A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • A. M. Васильцов A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • А. И. Михалева A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • А. В. Афонин A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • И. А. Ушаков A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033

DOI:

https://doi.org/10.1007/8271

Keywords:

acetylene, 3-acylpyrroles, O-vinyloximes, 1-vinylpyrroles, dioximes of 1, 3-diketones, isoxazoles

Abstract

Dioximes of 1,3-diketones enter into the Trofimov  reaction forming pyrroles containing an acyl or an O-vinyloxime substituent in position 3 of the pyrrole. In the case of sterically hindered dioximes the main reaction products are isoxazoles.

How to Cite
Zaitsev, A. B.; Schmidt, E. Yu.; Mikhaleva, A. M.; Afonin, A. V.; Ushakov, I. A  Chem. Heterocycl. Compd. 2005, 41, 722. [Khim. Geterotsikl. Soedin. 2005, 839.]

For this article in the English edition, see DOI 10.1007/s10593-005-0212-6

 

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Published

2023-11-07

Issue

No. 6 (2005)

Section

Original Papers