INVESTIGATION OF THE PRODUCTS OF INTERACTION OF CYCLIC DIKETONES WITH NITROGEN-CONTAINING 1,4-BINUCLEOPHILES

Authors

  • Н. Н. Колос Kharkov V. N. Karazin National University, Kharkov 61077
  • Е. Н. Юрченко Kharkov V. N. Karazin National University, Kharkov 61077
  • В. Д. Орлов Kharkov V. N. Karazin National University, Kharkov 61077
  • С. В. Шишкина Kharkov V. N. Karazin National University, Kharkov 61077
  • О. В. Шишкин Kharkov V. N. Karazin National University, Kharkov 61077

DOI:

https://doi.org/10.1007/8422

Keywords:

o-aminophenol, arylbis(5, 5-dimethylcyclohexane-1, 3-dion-2-yl)methanes, hexahydrodibenzo[b, e]-1, 4-diazepin-1-ones, decahydroacridine-1, 8-diones, dimedone, o-phenylenediamine, cyclocondensation

Abstract

The interaction of arylbis(5,5-dimethylcyclohexane-1,3-dion-2-yl)methanes with o-phenylenediamine and o-aminophenol leads to the preparation of 3,3-dimethyl-11-aryl-2,3,4,5,10,11-hexahydrobenzo[b,e]-1,4-diazepin-1-ones and 3,3,6,6-tetramethyl-9-aryl-10-(2-hydroxyphenyl)-2,4,5,7,9-decahydroacridine-1,8-diones respectively.  A one-pot method is proposed for the synthesis of derivatives of hexahydrodibenzo[b,e]-1,4-diazepin-1-ones. The structure of the first member of this series was confirmed by X-ray diffraction analysis.

How to Cite
Kolos, N. N.; Yurchenko, E. N.; Orlov, V. D.; Shishkina, S. V.; Shishkin, O. V.  Chem. Heterocycl. Compd. 2004, 40, 1550. [Khim. Geterotsikl. Soedin. 2004, 1798.]

For this article in the English edition, see DOI 10.1007/s10593-005-0098-3

 

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Published

2023-12-08

Issue

No. 12 (2004)

Section

Original Papers