REACTIONS OF 2-(2-HETARYL)-2-(TETRAHYDROFURAN-2-YLIDENE)ACETONITRILES WITH TERTIARY AMINES

Authors

  • Д. С. Милохов Kyiv Taras Shevchenko National University
  • О. В. Хиля Kyiv Taras Shevchenko National University
  • А. В. Туров Kyiv Taras Shevchenko National University
  • Р. И. Зубатюк Scientific-Technological Complex "Institute of Monocrystals", National Academy of Sciences of Ukraine
  • Г. В. Паламарчук Scientific-Technological Complex "Institute of Monocrystals", National Academy of Sciences of Ukraine
  • О. В. Шишкин Scientific-Technological Complex "Institute of Monocrystals", National Academy of Sciences of Ukraine
  • А. А. Чекотило Kyiv Taras Shevchenko National University
  • Ю. М. Воловенко Kyiv Taras Shevchenko National University

DOI:

https://doi.org/10.1007/847

Keywords:

5-(4-aza-1-azoniobicyclo[2.2.2]oct-1-yl)-1-cyano-1-(2-hetaryl)pent-1-en-2-olates, betaines, 1-cyano-1 (2-hetaryl)-5-(pyridinium-1-yl)-1-penten-2-olates, diazabicyclo[2.2.2]octane, 2-(2-hetaryl)-2-(tetra-hydrofuran-2-ylidene)acetonitriles, pyridine, tertiary amines, N-nucleophiles

Abstract

The reactions of 2-(2-hetaryl)-2-(tetrahydrofuran-2-ylidene)acetonitriles with conformationally rigid and heterocyclic tertiary amines were investigated. Compounds with bipolar structures were obtained: 1-cyano-1-(2-hetaryl)-5-(pyridinium-1-yl)-1-penten-2-olates and 5-(4-aza-1-azoniobicyclo[2.2.2]oct-1‑yl)-1-cyano-1-(2-hetaryl)pent-1-en-2-olates.

Authors: D. S. Milokhov, O. V. Khilya, A. V. Turov, R. I. Zubatyuk, G. V. Palamarchuk, O. V. Shishkin, A. A. Chekotilo, and Yu. M. Volovenko

English Translation in Chemistry of Heterocyclic Compounds, 2013, 48 (12), pp 1761-1769

http://link.springer.com/article/10.1007/s10593-013-1207-3

Downloads

Published

2013-08-19

Issue

No. 12 (2012)

Section

Original Papers