SYNTHESIS AND ROTAMERISM OF 9,10-DIARYL-SUBSTITUTED 1,2,3,4,5,6,7,8,9,10-DECAHYDROACRIDINE-1,8-DIONES

Authors

  • В. А. Чебанов NTK Institute for Single Crystals, Kharkov 61001
  • В. Е. Сараев НТК "Институт монокристаллов", Харьков 61001
  • К. М. Кобзарь NTK Institute for Single Crystals, Kharkov 61001
  • С. М. Десенко NTK Institute for Single Crystals, Kharkov 61001
  • В. Д. Орлов V. N. Karazin National University, Kharkov 61070
  • Е. А. Гура NTK Institute for Single Crystals, Kharkov 61001

Keywords:

diaryl-substituted decahydroacridinediones, heterocyclization, rotamerism

Abstract

Condensation of aromatic aldehydes with 5,5-dimethylcylohexane-1,3-dione and primary arylamines gave 9,10-diaryl-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-diones. Several stereochemical features of the synthesized compounds are discussed. Dynamic NMR was used to determine the inversion barriers for the rotamers formed.

How to Cite
Chebanov, V. A.; Saraev, V. E.; Kobzar', K. M.; Desenko, S. M.; Orlov, V. D.; Gura, E. A. Chem. Heterocycl. Compd. 2004, 40, 475. [Khim. Geterotsikl. Soedin. 2004, 571.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000033541.49115.a0

Downloads

Published

2004-04-25

Issue

No. 4 (2004)

Section

Original Papers