SOME CONVERSIONS OF THIAZOLINE CARBOXYLIC ACID ESTERS
Keywords:
3,4-dimethyl-2-thioxothiazoline-5-carboxylic acid hydrazide, N-(3,4-dimethyl-2-thioxothiazolinylcarbonyl)hydrazones of aromatic and heteroaromatic aldehydes, acetophenone and p-benzoquinone, 3-aryl-4-methyl-2-thioxo-1,3-thiazoline-5-carboxylic acid esters, solvolysisAbstract
We have carried out solvolysis of the previously described ethyl esters of 3-methyl(aryl)-4-methyl-2-thioxothiazoline-5-carboxylic acids, leading to the corresponding acids without breaking down the heterocycle. We synthesized a series of novel esters from the latter by treatment with dimethyl sulfate or reactive halides. Of these, only in the case of the ethyl ester of 3,4-dimethyl-2-thioxothiazoline-5-carboxylic acid did we obtain the hydrazinolysis product (the hydrazide), from which we synthesized novel hydrazones by treatment with aldehydes and ketones.
How to Cite
Dovlatyan, V. V.; Eliazyan, K. A.; Pivazyan, V. A.; Engoyan, A. P. Chem. Heterocycl. Compd. 2003, 39, 1238. [Khim. Geterotsikl. Soedin. 2003, 1409.]
For this article in the English edition, see DOI 10.1023/B:COHC.0000008273.38554.9a
