<i>S<sub>RN</i></sub>1 REACTIONS IN NITROBENZO[1,3]DIOXOLE SERIES

Authors

  • J. Meuche-Albeny Laboratoire de Chimie Organique, UMR CNRS 6517, Faculté de Pharmacie, 13385 Marseille
  • P. Rathelot Laboratoire de Chimie Organique, UMR CNRS 6517, Faculté de Pharmacie, 13385 Marseille
  • M. P. Crozet Laboratoire de Chimie Organique, UMR CNRS 6517, Faculté de Pharmacie, 13385 Marseille
  • P. Vanelle Laboratoire de Chimie Organique, UMR CNRS 6517, Faculté de Pharmacie, 13385 Marseille

Keywords:

nitrobenzo[1,3]dioxole, nitronate anion, C-alkylation, SRN1 reaction

Abstract

5-Chloromethyl-6-nitrobenzo[1,3]dioxole has been shown to react with 2-nitropropane anion to give C-alkylation by an SRN1 mechanism. The reaction was extended to various aliphatic, cyclic and heterocyclic nitronate anions, leading to a new series of nitrobenzo[1,3]dioxole derivatives.

How to Cite
Meuche-Albeny, J.; Rathelot, P.; Crozet, M. P.; Vanelle, P. Chem. Heterocycl. Compd. 2003, 39, 989. [Khim. Geterotsikl. Soedin. 2003, 11`39.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000003513.53760.fb

Downloads

Published

2003-08-25

Issue

No. 8 (2003)

Section

Original Papers