NOVEL FLUORINE CONTAINING TETRATHIAFULVALENES FOR THE PREPARATION OF LANGMUIR–BLODGETT FILMS

Authors

  • Г. Г. Абашев Natural Sciences Institute, Perm State University, Perm 614600
  • Е. В. Шкляева Natural Sciences Institute, Perm State University, Perm 614600
  • А. Г. Тенишев Natural Sciences Institute, Perm State University, Perm 614600
  • Д. Н. Кореков OOO Scientific Introduction Firm "Okta", Perm 614000

Keywords:

1,3-dithiol-2-ones, 1,3-dithiole-2-thiones, fluorinated benzylthiotetrathiafulvalenes, cyclic voltamograms

Abstract

The novel fluorinated tetrathiafulvalenes: tetra(2,3,5,6-tetrafluorobenzylthio)-, dimethyldi(2,3,4,5,6-pentafluorobenzylthio)-, dimethyldi(2,3,5,6-tetrafluorobenzylthio)-, dimethyldi[3,5-di(trifluoromethyl)-benzylthio]-, and dimethyldi(2-fluoro-4-bromobenzylthio)tetrathiafulvalenes have been synthesized in order to prepare Langmuir–Blodgett films. Their cyclic voltamograms have been studied and these show two, reversible, one-electron oxidation waves. A novel series of fluorinated benzylthio- and benzoylthio-1,3-dithiole-2-thiones and -2-ones has been synthesized.

How to Cite
Abashev, G. G.; Shklyaeva, E. V.; Tenishev, A. G.; Korekov, D. N. Chem. Heterocycl. Compd. 2003, 39, 760. [Khim. Geterotsikl. Soedin. 2003, 888.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1025647112804

Published

2003-06-25

Issue

Section

Original Papers