SYNTHESIS OF DERIVATIVES OF OF ∆<sup>2</sup> -IMIDAZOLIN-5-ONE AND IMIDAZOLIDINE CONTAINING RESIDUES OF STERICALLY-HINDERED PHENOLS

Authors

  • В. И. Келарев I. M. Gubkin Oil and Gas State University, Moscow 117917
  • М. А. Силин I. M. Gubkin Oil and Gas State University, Moscow 117917
  • О. А. Борисова I. M. Gubkin Oil and Gas State University, Moscow 117917

Keywords:

azomethines, N-acylhydrazones, imidazolidines, imidazolines, oxazolones, sterically-hindered phenols, condensation

Abstract

1-Substituted 4-benzylidene-2-{β-[3,5-di(tert-butyl)-4-hydroxyphenyl]-vinyl}-4-benzylidene-∆2-imidazolin-5-ones have been synthesized by the interaction of azomethines and N-acylhydrazones (derivatives of 3,5-di(tert-butyl)-4-hydroxybenzaldehyde) with 4-benzylidene-2-methyloxazol-5-one. The acylation of 1,2-bis[3,5-di(tert-butyl)-4-hydroxy-benzylideneamino]ethane with acid chlorides in acetonitrile in the presence of triethylamine leads to 1,3-diacyl-2-[3,5-di(tert-butyl)-4-hydroxyphenyl]imidazolidine.

How to Cite
Kelarev, V. I.; Silin, M. A.; Borisova, O. A. Chem. Heterocycl. Compd. 2003, 39, 729. [Khim. Geterotsikl. Soedin. 2003, 856.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1025686826917

Published

2003-06-25

Issue

Section

Original Papers