Hexahydro-8-isoquinolones with electron-acceptor substituents in position 4

Authors

  • Я. Озолс Latvian Institute of Organic Synthesis, Riga LV-1006
  • Б. Виганте Latvian Institute of Organic Synthesis, Riga LV-1006
  • Л. Баумане Latvian Institute of Organic Synthesis, Riga LV-1006
  • А. Мишнeв Latvian Institute of Organic Synthesis, Riga LV-1006
  • И. Tyрoвскис Latvian Institute of Organic Synthesis, Riga LV-1006
  • Г. Дубурс Latvian Institute of Organic Synthesis, Riga LV-1006
  • Я. Страдынь Latvian Institute of Organic Synthesis, Riga LV-1006

Abstract

By the interaction of 2-acetyl-5,5-dimethyl-2-cyclohexen-1-one with certain nitroenamines, a number of hexahydro-8-isoquinolones with a nitro group in position 4 have been obtained; potentials of their electrochemical oxidation have been determined, and a possible mechanism and manifestation of structural effects in this process have been suggested and discussed. The structure of 1,3,6,6-tetramethyl-4-nitro-2, 4a-5,6,7,8-hexahydro-8-isoquinolone has been established by means of X-ray diffraction analysis.

How to Cite
Ozols, Y.; Vigante, B.; Baumane, L.; Mishnev, A.; Turovskis, I.; Duburs, G.; Stradyn', Ya Chem. Heterocycl. Compd. 1998, 34, 1166. [Khim. Geterotsikl. Soedin. 1998, 34, 1372.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02319495

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Published

1998-10-25

Issue

No. 10 (1998)

Section

Original Papers