Regioorientation in the reaction of side chain activated alkylpyridines with electrophiles

Authors

  • М. А. Юровскaя M. V. Lomonosov Moscow State University, Moscow 119899
  • И. Г. Хамлова M. V. Lomonosov Moscow State University, Moscow 119899
  • В. H. Нестеров A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 117813
  • O. B. Шишкин M. V. Lomonosov Moscow State University, Moscow 119899
  • Ю. T. Стручков A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 117813

Abstract

X-ray structural data has shown that condensation of sym-3-nitrocollidine with benzaldehyde occurs at the 6-methyl group. The presence of an acceptor group in the side chain of 2,6-dimethyl-4-cyanomethyl-3-nitropyridine causes condensation to occur at the activated methylene group in the 4-position.

How to Cite
Yurovskaya, M. A.; Khamlova, I. G.; Nesterov, V. N.; Shishkin, O. V.; Struchkov, Yu. T. Chem. Heterocycl. Compd. 1995, 31, 1339. [Khim. Geterotsikl. Soedin. 1995, 1543.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01168629

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Published

1995-11-25

Issue

No. 11 (1995)

Section

Original Papers