REGIOSELECTIVE SYNTHESIS OF 1,5-DIARYL-2-(HYDROXYALKYL)-8-METHYLGLYCOLURILS

Authors

  • М. М. Антонова N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • В. В. Баранов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Ю. В. Нелюбина A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
  • А. Н. Кравченко N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1567

Keywords:

1, 5-diaryl-2-(hydroxyalkyl)-8-methylglycolurils, imidazooxazepinones, imidazooxazinones, imidazooxazolones, N-methylurea, regioselectivity

Abstract

The cyclocondensation of N-methylurea with derivatives of tetrahydroimidazooxazolone, tetrahydro-imidazooxazinone, dihydroimidazooxazinone, and tetrahydroimidazooxazepinone was studied for the first time. It was shown that the reactions take place with high regioselectivity, are regular in character, and lead to the formation of previously inaccessible 1,5-diaryl-2-(hydroxyalkyl)-8‑methylglycolurils with high yields.

How to Cite
Antonova, M. M.; Baranov, V. V.; Nelyubina, Yu. V.; Kravchenko, A. N. Chem. Heterocycl. Compd. 2014, 50, 503. [Khim. Geterotsikl. Soedin. 2014, 551.]

For this article in the English edition see DOI 10.1007/s10593-014-1501-8

Author Biographies

М. М. Антонова, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Мария Михайловна Антонова

инженер-исследователь, лаборатория азотсодержащих соединений

В. В. Баранов, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Владимир Владимирович Баранов

научный сотрудник, кандидат химических наук, лаборатория азотсодержащих соединений

Ю. В. Нелюбина, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Юлия Владимировна Владимировна

старший научный сотрудник, лаборатория рентгеноструктурных исследований

А. Н. Кравченко, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Ангелина Николаевна Кравченко

ведущий научный сотрудник ИОХ РАН, зам. зав. лаборатории азотсодержащих соединений № 19

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Published

2014-05-14

Issue

No. 4 (2014)

Section

Original Papers