Sigma complexes in the pyrimidine series. 12. Acylation and ethoxycarbonylation of acetonyl anionic sigma complexes of 5-nitropyrimidine

Authors

  • С. Г. Вишневский Institute of Bioorganic Chemistry and Petroleum Chemistry, National Academy of Sciences of Ukraine, 253660, Kiev
  • B. B. Пироженко Institute of Bioorganic Chemistry and Petroleum Chemistry, National Academy of Sciences of Ukraine, 253660, Kiev
  • Г. Я. Ременников Institute of Bioorganic Chemistry and Petroleum Chemistry, National Academy of Sciences of Ukraine, 253660, Kiev

Abstract

As a result of acylation and ethoxycarbonylation of acetonyl anionic sigma complexes of 5-nitropyrinddine containing a geminal unit in the 6 and 2 positions, we have obtained N(1)-substituted 5-nitro-1,6-dihydropyrimidines and C(5)-substituted pyrimidines respectively.

How to Cite
Vishnevskii, S. G.; Pirozhenko, V. V.; Remennikov, G. Y. Chem. Heterocycl. Compd. 1996, 32, 68. [Khim. Geterotsikl. Soedin. 1996, 77.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01169357

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Published

1996-01-25

Issue

No. 1 (1996)

Section

Original Papers