CYCLOADDITION OF DI(2-PYRIDYL) DITELLURIDE TO NORBORNENE STIMULATED BY ANTIMONY PENTACHLORIDE

Authors

  • А. В. Борисов R. E. Alekseev Nizhny Novgorod State Technical University
  • Ж. В. Мацулевич R. E. Alekseev Nizhny Novgorod State Technical University
  • В. К. Османов R. E. Alekseev Nizhny Novgorod State Technical University
  • Г. Н. Борисова R. E. Alekseev Nizhny Novgorod State Technical University
  • Г. З. Мамедова Baku State University
  • А. М. Магеррамов Baku State University
  • В. Н. Хрусталев A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1137

Keywords:

alkenes, antimony pentachloride, di(2-pyridyl) ditelluride, tellurium-containing heterocycles, polar cycloaddition

Abstract

The interaction of norbornene with the di(2-pyridyl) ditelluride–antimony pentachloride system in methylene chloride proceeds with the formation of exo-9-telluro-3-azoniatetracyclo-[9.2.1.02.10.03,8]tetradeca-3(8),4,6-triene chloroantimonates(III), which are the products of polar cycloaddition of tellurium-containing electrophiles at the multiple bond. The structure of the heterocyclization products was established by X-ray structural analysis.

Authors: A. V. Borisov, Zh. V. Matsulevich, V. K. Osmanov, G. N. Borisova, G. Z. Mammadova, A. M. Maharramov, and V. N. Khrustalev.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (7), pp 1085-1089

http://link.springer.com/article/10.1007/s10593-012-1103-2

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Published

2013-11-07

Issue

No. 7 (2012)

Section

Original Papers