SULFENYL HALIDES IN THE SYNTHESIS OF HETEROCYCLES. 4. HETEROCYCLIZATION IN REACTIONS OF ALKENES WITH SULFENYLATING REAGENTS BASED ON DI(2-PYRIDYL) DISULFIDE

Authors

  • А. В. Борисов R. E. Aleeksev Nizhny Novgorod State Technical University
  • Ж. В. Мацулевич R. E. Aleeksev Nizhny Novgorod State Technical University
  • В. К. Османов R. E. Aleeksev Nizhny Novgorod State Technical University
  • Г. Н. Борисова R. E. Aleeksev Nizhny Novgorod State Technical University
  • Г. З. Мамедова Baku State University
  • А. М. Магеррамов Baku State University
  • В. Н. Хрусталев A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1140

Keywords:

alkenes, di(2-pyridyl) disulfide, sulfenyl chlorides, heterocyclization

Abstract

Sulfenylating reagents have been obtained by the action of sulfuryl chloride or antimony pentachloride on di(2-pyridyl) disulfide. Their interaction with alkenes proceeds as addition-cyclization with ring closure by the nitrogen atom of the pyridine fragment of the sulfur-containing electrophile with the formation of 2,3-dihydro[1,3]thiazolo[3,2-a]pyridinium derivatives.

Authors: A. V. Borisov, Zh. V. Matsulevich, V. K. Osmanov, G. N. Borisova, G. Z. Mammadova, A. M. Maharramov, and V. N. Khrustalev.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (7), pp 1098-1104

http://link.springer.com/article/10.1007/s10593-012-1104-1

Published

2013-11-07

Issue

Section

Original Papers