GRINDING-INDUCED SYNTHESIS OF HETEROCYCLIC FULLERENE DERIVATIVES UNDER SOLVENT-FREE CONDITIONS

Authors

  • Javad Safaei-Ghomi University of Kashan
  • Reihaneh Masoomi University of Kashan

DOI:

https://doi.org/10.1007/2011

Keywords:

fullerene, fulleroisoxazoline, fulleropyrazoline, cycloaddition reaction, grinding, solvent-free synthesis

Abstract

In this research, a green, easy, and effective solvent-free procedure for the synthesis of heterocyclic fullerene derivatives has been achieved via 1,3-dipolar cycloaddition reaction of C60, substituted arylhydrazones/oximes, and PhI(OAc)2 under grinding as a simple physical-mechanical method. This approach does not involve any hazardous organic solvent and has various advantages including design of safe reaction conditions moderate to good yields and short reaction times.

How to Cite
Safaei-Ghomi, J.; Masoomi, R. Chem. Heterocycl. Compd. 2015, 51, 39. [Khim. Geterotsikl. Soedin. 2015, 51, 39.]

For this article in the English edition see DOI 10.1007/s10593-015-1657-x

Author Biographies

Javad Safaei-Ghomi, University of Kashan

Department of Organic Chemistry,
Faculty of Chemistry, University of Kashan,
Kashan, P.O. Box 87317-51167, I. R. Iran

Reihaneh Masoomi, University of Kashan

Department of Organic Chemistry,
Faculty of Chemistry, University of Kashan,
Kashan, P.O. Box 87317-51167, I. R. Iran

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Published

2015-02-04

Issue

Vol. 51 No. 1 (2015)

Section

Original Papers