REGIOSELECTIVE N-ARYLATION OF NITROAZOLES. DETERMINATION OF THE STRUCTURE OF N-ARYLNITROAZOLES ON THE BASIS OF NMR SPECTROSCOPIC DATA AND QUANTUM-CHEMICAL CALCULATIONS

Authors

  • В. А. Чертков Moscow M. V. Lomonosov State University
  • А. К. Шестакова Russian Federation State Science Center, State Research Institute of Chemistry and Technology of Organoelement Compounds
  • Д. В. Давыдов Moscow M. V. Lomonosov State University

DOI:

https://doi.org/10.1007/2174

Keywords:

diaryliodonium salts, CuI, nitroazoles, regioselective N-arylation, two-dimensional NMR, catalysis, quantum-chemical calculations, microwave irradiation, high resolution NMR, NOE factors

Abstract

The N-arylation of a series of nitroazoles has been studied with the aid of diaryliodonium salts in the presence of CuI under the action of microwave radiation. It was found that alkylation proceeds regioselectively in each actual case with the formation of one of two possible isomers. The correct structure of the N-arylation products was established on the basis of NMR spectroscopy.

How to Cite
Chertkov, V. A.; Shestakova, A. K.; Davydov, D. V. Chem. Heterocycl. Compd. 2011, 47(1), 45. [Khim. Geterotsikl. Soedin. 2011, 63.]

For this article in the English edition see DOI 10.1007/s10593-011-0718-z

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Published

2014-12-18

Issue

No. 1 (2011)

Section

Original Papers