NEW DOMINO DIMERIZATION OF CYCLOPROPYLINDOLES: SYNTHESIS OF 1,3-BIS(INDOLYL)CYCLOPENTANES

Authors

  • Ольга А. Иванова M. V. Lomonosov Moscow State University; Federal Research Center of Pediatric Hematology, Oncology, and Immunology named after D. Rogachev
  • Екатерина М. Будынина M. V. Lomonosov Moscow State University; Federal Research Center of Pediatric Hematology, Oncology, and Immunology named after D. Rogachev
  • Виктор Н. Хрусталев A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Peoples' Friendship University of Russia
  • Игорь В. Трушков M. V. Lomonosov Moscow State University; Federal Research Center of Pediatric Hematology, Oncology, and Immunology named after D. Rogachev
  • Михаил Я. Мельников M. V. Lomonosov Moscow State University

DOI:

https://doi.org/10.1007/2655

Keywords:

donor-acceptor cyclopropanes, indole, Lewis acids, dimerization

Abstract

The diester of 2-(1-benzyl-2-methylindol-3-yl)cyclopropane-1,1-dicarboxylic acid undergoes a domino reaction in the presence of titanium(IV) chloride, forming an unusual [3+2] cyclodimer, 1,3-bis(indolyl)cyclopentane.

How to Cite
Ivanova, O. А.; Budynina, E. M.; Khrustalev, V. N.; Trushkov, I. V.; Melnikov, M. Ya. Chem. Heterocycl. Compd. 2015, 51, 936. [Khim. Geterotsikl. Soedin. 2015, 51, 936.]

For this article in the English edition see DOI 10.1007/s10593-015-1798-y

 

Author Biographies

Ольга А. Иванова, M. V. Lomonosov Moscow State University; Federal Research Center of Pediatric Hematology, Oncology, and Immunology named after D. Rogachev

Ольга Александровна Иванова

старший научный сотрудник, кафедра химической кинетики

Екатерина М. Будынина, M. V. Lomonosov Moscow State University; Federal Research Center of Pediatric Hematology, Oncology, and Immunology named after D. Rogachev

Екатерина Михайловна Будынина

ведущий научный сотрудник, кафедра химической кинетики

Виктор Н. Хрусталев, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Peoples' Friendship University of Russia

Виктор Николаевич Хрусталев

ведущий научный сотрудник, лаборатория рентгеноструктурных исследований

Игорь В. Трушков, M. V. Lomonosov Moscow State University; Federal Research Center of Pediatric Hematology, Oncology, and Immunology named after D. Rogachev

Игорь Викторович Трушков

ведущий научный сотрудник, кафедра химической кинетики

Михаил Я. Мельников, M. V. Lomonosov Moscow State University

Михаил Яковлевич Мельников

заведующий кафедрой химической кинетики

Downloads

Published

2015-10-29

Issue

Vol. 51 No. 10 (2015)

Section

Letters to the Editor