HETEROCYCLIZATION OF 1- AND 2-ALKYNYL-9,10-ANTHRAQUINONES: NEW SYNTHETIC AND MECHANISTIC ASPECTS

Authors

  • С. Ф. Василевский Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences
  • Д. С. Баранов Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/338

Keywords:

alkynes, 9, 10-anthraquinone, nitrogen heterocycles, cyclization, mechanisms, reactivity, rearrangements

Abstract

New data (2005-2012) on the peculiarities and common characteristics of cascade reactions of 1- and 2 alkynyl-9,10-anthraquinones with polyfunctional reagents (guanidine, urea, thiourea) and also intramolecular heterocyclizations of ortho-amino derivatives of 1- and 2-alkynyl-9,10-anthraquinones are reviewed. Mechanisms for new reactions are suggested.

Authors: S. F. Vasilevskiy and D. S. Baranov

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (1), pp 140-151

http://link.springer.com/article/10.1007/s10593-013-1235-z

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Published

2013-02-21

Issue

No. 1 (2013)

Section

Review Articles