SYNTHESIS OF MONOSUBSTITUTED 1,2,4,5-TETRAZINES – 3-AMINO-1,2,4,5-TETRAZINES

Authors

  • Геннадий Ф. Рудаков D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047
  • Юрий А. Моисеенко D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047
  • Наталия А. Спесивцева D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047

DOI:

https://doi.org/10.1007/3769

Keywords:

ditetrazinylamines, N, N-di(1, 2, 4, 5-tetrazin-3-yl)-1, 5-tetrazin-3-amine, nitroguanidine, 1, 5-tetrazine, 1H-tetrazol-5-amine, 1H-1, 4-triazol-5-amine, nucleophilic substitution

Abstract

The substitution of pyrazolyl moiety in 3-(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine with N-nucleophiles provided a series of high-nitrogen tetrazine derivatives, including 2-nitro-1-(1,2,4,5-tetrazin-3-yl)guanidine, N-(1H-tetrazol-5-yl)-1,2,4,5-tetrazin-3-amine, N-(1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazin-3-amine, N,N'-di(1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazine-3,6-diamine, N-(1,2,4,5-tetrazin-3-yl)[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-amine, and tritetrazinylamine. The thermal stability of these new compounds was evaluated by differential scanning calorimetry and their energetic characteristics were calculated.

Authors: Gennady F. Rudakov*, Yurii A. Moiseenko, Natal'ya А. Spesivtseva

Author Biographies

Геннадий Ф. Рудаков, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047

старший преподаватель кафеды "Химии и технологии органических соединений азота"

Юрий А. Моисеенко, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047

студент

Наталия А. Спесивцева, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047

студент

Downloads

Published

2017-08-18

Issue

Vol. 53 No. 6/7 (2017): Heterocycle-based energetic materials

Section

Original Papers