3-ALKYL-4-NITROFURAZANS – PLASTICIZERS FOR POLYMERS

Authors

  • Юрий М. Лотменцев D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047,
  • Наталья Н. Кондакова D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047,
  • Артём В. Бакешко D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047,
  • Андрей М. Козеев N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Алексей Б. Шереметев N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

DOI:

https://doi.org/10.1007/3779

Keywords:

nitrofurazans, compatibility with polymers, glass transition, melting, volatility

Abstract

Oxidation of 4-alkylfurazan-3-amines to the corresponding nitrofurazans was achieved using mixtures of hydrogen peroxide. The volatility of the products as a function of the size of substituent R, has been studied. The phase and relaxation transitions were characterized and the thermodynamic compatibility with polyester urethane was established. The melting points and melting enthalpies of alkylnitrofurazans were determined.

Authors: Yury M. Lotmentsev*, Natalya N. Kondakova, Artem V. Bakeshko, Andrei M. Kozeev, Aleksei B. Sheremetev

 

Author Biographies

Юрий М. Лотменцев, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047,

Главный научный сотрудник кафедры химии и технологии высокомолекулярных соединений, доктор техничнеских наук, профессор

Наталья Н. Кондакова, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047,

Кафедра химии и технологии высокомолекулярных соединений. ведущий инженер

Артём В. Бакешко, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047,

Кафедра химии и технологии высокомолекулярных соединений. студент

Андрей М. Козеев, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

младший научный сотрудник

Алексей Б. Шереметев, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

Ведущий гаучныц сотрудник

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Published

2017-08-18

Issue

Vol. 53 No. 6/7 (2017): Heterocycle-based energetic materials

Section

Original Papers