NITROGEN HETEROCYCLIC SALTS OF POLYHEDRAL BORANE ANIONS: FROM IONIC LIQUIDS TO ENERGETIC MATERIALS

Authors

  • Игорь Б. Сиваев A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., Moscow 119991

DOI:

https://doi.org/10.1007/3783

Keywords:

carba-closo-dodecaborate anion, closo-decaborate anion,  closo-dodecaborate anion, cobalt bis(dicarbollide), nitrogen heterocyclic cations, polyhedral boron hydrides, energetic materials, ionic liquids

Abstract

Synthesis, structure, and physical properties of nitrogen heterocyclic salts of the polyhedral borane anions (closo-decaborate [B10H10]2–, closo-dodecaborate [B12H12]2–, carba-closo-dodecaborate [CB11H12]–, and 3,3'-cobaltabis(1,2-dicarbollide) [3,3'-Co(1,2-C2B9H11)2]–)  and their derivatives, including their potential application as ionic liquids and energetic materials, are reviewed.

Author: Igor B. Sivaev

Author Biography

Игорь Б. Сиваев, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., Moscow 119991

Laboratory of Organoaluminium and Organoboron Compounds

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Published

2017-08-15

Issue

Vol. 53 No. 6/7 (2017): Heterocycle-based energetic materials

Section

Review Articles