SYNTHESIS AND STRUCTURE OF NOVEL Si-SUBSTITUTED SILYLPROPYL DERIVATIVES OF 2-MERCAPTOBENZOXAZOLE AND 2-MERCAPTOBENZOTHIAZOLE

Authors

  • Екатерина A. Гребнева Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Юлия И. Болгова Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Ольга М. Трофимова Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Александр И. Албанов Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Татьяна Н. Бородина Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia

DOI:

https://doi.org/10.1007/4960

Keywords:

(3-chloropropyl)trimethoxysilane, 2-mercaptobenzoxazole, 2-mercaptobenzotriazole, silatrane, trifluorosilane.

Abstract

A previously unknown carbofunctional (trimethoxysilyl)propyl derivative of the 2-mercaptobenzoxazole, C6H4NOCS(CH2)3Si(OMe)3, containing a tetracoordinated silicon atom was synthesized by nucleophilic substitution of the chlorine atom in the (3-chloropropyl)trimethoxysilane with the benzoxazol-2-ylsulfanyl group. The reaction of 2-[(trimethoxysilyl)propylsulfanyl]benzoxazole or -benzothiazole with boron trifluoride etherate led to a previously unknown hydrolytically unstable Si-fluoropropyl derivatives of 2-mercaptobenzoxazole or 2-mercaptobenzothiazole,  C6H4N(Y)CS(CH2)3SiF3 (Y = O, S). By transesterification of 2-[(trimethoxysilyl)-
propylsulfanyl]benzoxazole by tris(2-hydroxyethyl)amine, a new silatranylpropyl derivative of 2-mercaptobenzoxazole containing an intramolecular coordination bond N→Si and a pentacoordinated silicon atom, C6H4NOCS(CH2)3Si(OCH2CH2)3N, was obtained.

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Published

2019-08-14

Issue

Vol. 55 No. 8 (2019)

Section

Original Papers