SILACYCLOPHANONES. 3. CYCLIC ORGANOSILICON ESTERS OF <i>ortho</i>-PHTHALIC ACIDS

Authors

  • Сергей В. Басенко A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033
  • Анастасия С. Солдатенко A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033
  • Александр В. Ващенко A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033
  • Владимир И. Смирнов A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033

DOI:

https://doi.org/10.1007/5216

Keywords:

dichloro(chloromethyl)methylsilane, dichlorodimethylsilane, dichloro(methyl)phenylsilane, phthalic acid, 2, 3, 4, 5-tetrafluorophthalic acid, cyclic carboxylic esters, trimethylsilyl carboxylic esters

Abstract

Reactions of dichlorodimethylsilane with 2,3,4,5-tetrafluorophthalic acid bis(trimethylsilyl) ether (1:1, 20°C, 24 h) without a solvent and dichloro(chloromethyl)methylsilane and dichloro(methyl)phenylsilane with bis(trimethylsilyl) ester of ortho-phthalic acid (1:1, 20°C, 168–264 h) in hexane lead to the formation of previously unknown 14-membered cyclic organosilicon esters of ortho-phthalic acids (silacyclophanones) in 36–85% yields. Molecular structures of 14-membered cyclic ethers 4,10-dimethyl-4,10-diphenyl-3,5,9,11-tetraoxo-4,10-disyla-1,7(1,2)-dibenzacyclododecaphane-2,6,8,12-tetraone, 4,4,10,10-tetramethyl-3,5,9,11-tetraoxo-4,10-disila-1,7(1,2)-di(tetrafluorobenza)cyclododecaphane-2,6,8,12-tetraone, along with bis(trimethylsilyl) esters of 2,3,4,5-tetrafluorophthalic and orthophthalic acids, were studied by X-ray structural analysis.

Authors: Sergey V. Basenko*, Anastasiya S. Soldatenko, Aleksandr V. Vashchenko, Vladimir I. Smirnov

Author Biographies

Сергей В. Басенко, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033

главный научный сотрудник

Анастасия С. Солдатенко, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033

младший научный сотрудник

Александр В. Ващенко, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033

старший научный сотрудник

Владимир И. Смирнов, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033

заведующий лабораторией структурных исследований

Downloads

Published

2019-11-12

Issue

Vol. 55 No. 11 (2019)

Section

Short Communications