SYNTHESIS OF BENZO[<i>c</i>][1,7]NAPHTHYRIDINE DERIVATIVES
Authors
Антон Л. Шацаускас
Omsk State Technical University,
11 Mira Ave., Omsk 644050, Russia;
Элина Р. Сайбулина
Dostoevsky Omsk State University,
55a Mira Ave., Omsk 644077, Russia
Юрий В. Гатилов
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences,
9 Akademika Lavrentieva Ave., Novosibirsk 630090, Russia
Novosibirsk State University,
2 Pirogova St., Novosibirsk 630090, Russia
Анастасия С. Костюченко
Omsk State Technical University,
11 Mira Ave., Omsk 644050, Russia;
Dostoevsky Omsk State University,
55a Mira Ave., Omsk 644077, Russia
Александр С. Фисюк
Omsk State Technical University,
11 Mira Ave., Omsk 644050, Russia;
Reactivity of 2-methyl-6-phenylbenzo[c][1,7]naphthyridine in alkylation, oxidation, and electrophilic substitution reactions has been studied. The reaction of 2-methyl-6-phenylbenzo[c][1,7]naphthyridines with POCl3 yielded the previously unknown 4-chloro-2-methyl-6-phenylbenzo[c]-[1,7]naphthyridine. Its dehalogenation and substitution of halogen by nitrogen and sulfur nucleophiles were studied.