TWO TYPES OF PRODUCTS IN THE REACTIONS OF 2-PYRIDINESULFENYL HALIDES WITH CYCLOALKENES AND CYCLOALKADIENES: SYNTHESIS OF NOVEL [1,3]THIAZOLO[3,2-<i>a</i>]PYRIDINIUM DERIVATIVES

Authors

  • Роман С. Ишигеев A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Владимир А. Потапов A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Ирина В. Шкурченко A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia Pedagogical Institute of Irkutsk State University, 6 Nizhnyaya Naberezhnaya St., Irkutsk 664003, Russia
  • Сергей В. Зинченко A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia
  • Светлана В. Амосова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia

DOI:

https://doi.org/10.1007/5978

Keywords:

cyclohexadiene, cyclooctadiene, cyclopentene, di(pyridin-2-yl) disulfide, norbornene, 2-pyridinesulfenyl bromide, 2-pyridinesulfenyl chloride, [1, 3]thiazolo[3, 2-a]pyridinium derivatives.

Abstract

The reactions of 2-pyridinesulfenyl halides with cyclopentene, 1,4-cyclohexadiene, 1,5-cyclooctadiene, 1,3-cyclooctadiene, and norbornene, depending on the structure of the alkene, the nature of the halogen, and the duration of the process, lead to the formation of two types of adducts, electrophilic addition products or condensed compounds, [1,3]thiazolo[3,2-a]pyridinium derivatives, in high yields.

Author Biographies

Роман С. Ишигеев, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia

Н.с. Иркутского института химии имени А. Е. Фаворского СО РАН

Владимир А. Потапов, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia

д.х.н., профессор,
заведующий лабораторией
халькогенорганических соединений
Иркутского института химии имени А. Е. Фаворского СО РАН

Ирина В. Шкурченко, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia Pedagogical Institute of Irkutsk State University, 6 Nizhnyaya Naberezhnaya St., Irkutsk 664003, Russia

К.х.н., н.с. Иркутского института химии имени А. Е. Фаворского СО РАН

Сергей В. Зинченко, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia

Н.с. Иркутского института химии имени А. Е. Фаворского СО РАН

Светлана В. Амосова, A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk 664033, Russia

Д.х.н., профессор Иркутского института химии имени А. Е. Фаворского СО РАН

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Published

2020-12-18

Issue

Vol. 56 No. 12 (2020)

Section

Original Papers