ACYL AND SULFONYL DERIVATIVES OF 3,5-DIAMINO-1-R-1,2,4-TRIAZOLES

Authors

  • В. М. Чернышев South-Russian State Technical University, Novocherkassk 346428
  • В. А. Ракитов South-Russian State Technical University, Novocherkassk 346428
  • В. А. Таранушич South-Russian State Technical University, Novocherkassk 346428
  • В. В. Блинов South-Russian State Technical University, Novocherkassk 346428

DOI:

https://doi.org/10.1007/8188

Keywords:

3-acylamino-5-amino-1-R-1, 2, 4-triazoles, 5-amino-3-sulfonylamino-1-R-1, amino-, 3, 5-diamino-1, 4-triazole, 5-diacylamino-1, 1, acylation, regioselectivity, structure

Abstract

3-Acylamino-5-amino-1-R-1,2,4-triazoles are formed regioselectively on acylating 3,5-diamino-1-R-1,2,4-triazoles with an equimolar amount of anhydrides, carboxylic acid chlorides, and sulfonyl chlorides. With an excess of anhydride and carboxylic acid chloride 3,5-diacylamino-1-R-1,2,4-triazoles are formed. 3-Acylamino-5-amino-1-R-1,2,4-triazoles do not interact with sulfonyl chlorides. The higher reactivity of the 3-amino group towards acylating  agents is determined by electronic and not steric factors.

How to Cite
Chernyshev, V. M.; Rakitov, V. A.; Taranushich, V. A.; Blinov, V. V.  Chem. Heterocycl. Compd. 2005, 41, 1139. [Khim. Geterotsikl. Soedin. 2005, 1342.]

For this article in the English edition, see DOI 10.1007/s10593-005-0293-2

 

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Published

2023-10-20

Issue

No. 9 (2005)

Section

Original Papers