INVESTIGATION IN THE AREA OF FURAN ACETAL COMPOUNDS. 13. SYNTHESIS AND STRUCTURE OF 1,3-DIOXACYCLANES BASED ON FURFURAL AND GLYCEROL

Authors

  • E. V. Gromachevskaya Kuban State Technological University, Krasnodar 350072
  • F. V. Kvitkovsky Kuban State Technological University, Krasnodar 350072
  • E. B. Usova Kuban State Technological University, Krasnodar 350072
  • V. G. Kulnevich Kuban State Technological University, Krasnodar 350072

Keywords:

glycerol, 1,3-dioxane, 1,3-dioxolane, stereoisomers, conformation

Abstract

The optimum conditions were found for the condensation of glycerol with furfural. It was shown that the reaction of glycerol with furfural gives a mixture of the cis and trans isomers of five- and six-membered furan 1,3-dioxacyclanes. The cis- and trans-5-hydroxy-2-furyl-1,3-dioxanes were isolated by column chromatography, and their stereochemical structure was established by IR and NMR spectroscopy.

How to Cite
Gromachevskaya, E. V.; Kvitkovsky, F. V.; Usova, E. B.; Kulnevich, V. G. Chem. Heterocycl. Compd. 2004, 40, 979. [Khim. Geterotsikl. Soedin. 2004, 1137.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000046685.17653.c4

Downloads

Published

2004-08-25

Issue

No. 8 (2004)

Section

Original Papers