DERIVATIVES OF <i>sym</i>-TRIAZINE. 1. SYNTHESIS AND CONVERSIONS OF QUATERNARY METHYLAMMONIUM SALTS OF 2-CHLORO-4,6-DISUBSTITUTED 1,3,5-TRIAZINES IN NUCLEOPHILIC SUBSTITUTION REACTIONS
Keywords:
4,6-dimorpholyl-2-oxo-1,2-dihydro-sym-triazine, 2-trimethylammonio-sym-triazine chloride, 2-cyano-sym-triazinesAbstract
New quaternary ammonium salts of monochloro-4,6-disubstituted 1,3,5-triazines have been obtained. These compounds are convenient synthons for the synthesis of new cyano, alkoxy, and other derivatives of sym-triazine. Some conversions of the synthesized salts have been studied. An elimination–isomerization reaction of the sym-triazine ring into a 2-oxo-1,2-dihydro-sym-triazine ring was discovered.
How to Cite
Chesniuk, A. A.; Mikhailichenko, S. N.; Zavodnov, V. S.; Zaplishny, V. N. Chem. Heterocycl. Compd. 2002, 38, 177. [Khim. Geterotsikl. Soedin. 2002, 197.]
For this article in the English edition, see DOI https://doi.org/10.1023/A:1015335124677