SYNTHESIS AND CHARACTERIZATION OF [РtМе<sub>3</sub>L(H<sub>2</sub>O)]BF<sub>4</sub>·Н<sub>2</sub>О (L=3-O-ACETYL-1,2-О-ISОРRОРYLIDENE-&alpha;-<i>D</i>-GLUCOFURANОSE)

Авторы

  • Henrik Junicke Editorial Office "Chemistry of Heterocyclic Compounds"
  • Clemens Bruhn Institut für Anorganische Chemie, Martin-Luther-Universität; Halle-Wittenberg
  • Christoph Wagner Institut für Anorganische Chemie, Martin-Luther-Universität; Halle-Wittenberg
  • Dirk Steinborn Institut für Anorganische Chemie, Martin-Luther-Universität; Halle-Wittenberg

DOI:

https://doi.org/10.1007/739

Аннотация

Reaction of [РtМе3(Ме2СО)3]BF4 (1) with 3-О-acetyl-1,2;5,6-di-О-isopropylidene-α-D-glucofuranose in acetone affords [PtMe3L]BF4 (2) (L = 3-O-aсеtyl-1,2-О-isoрropylidene-α-D-glucofurаnоse). In wet methylene chloride the complex 2 transforms to [РtМe3L(Н2O)]BF4·Н2O (3).

Complex 3 was characterized by microanalysis and NMR spectroscopy (1Н, 13С, 195Рt). The X-ray structure analysis (monoclinic, Р21, a = 10.529(3) Å, b = 7.322(2) Å, c = 14.668(4) Å, Z = 2) reveals that 3-О-acetyl-1,2-О-isopropylidene-α-D-glucofuranose acts as a neutral bidentate ligand which is coordinated via two hydroxyl groups (k2O5,6 coordination). The five-membered 1,3,2-diохaрlаtina rings exhibit an envelope conformation. The coordination sphere of platinum is completed by Н2O ligand.

Also published in Chemistry of Heterocyclic Compounds, 1999, 35 (8), pp 984-991

http://link.springer.com/article/10.1007/BF02252168

Загрузки

Опубликован

2013-06-20

Выпуск

№ 8 (1999)

Раздел

Оригинальные статьи