CORRELATION OF THE HOMO–LUMO GAP IN FURYL AND THIENYL NITRONES AND NITROETHENES WITH THEIR ELECTROCHEMICAL REDOX POTENTIALS

Авторы

  • M. Boulkroune Department of Chemistry, University Mentouri, 25000 Constantine, Algeria Pers. address: 122 Rue Kaddour Boumedous Bt D, Ciloc, Constantine, Algérie.
  • L. Ignatovich Laboratory of Metalloorganic Chemistry Latvian Institute of Organic Synthesis
  • V. Muravenko Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis
  • J. Spura Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis
  • A. Chibani Latvian Institute of Organic Synthesis
  • V. Jouikov UMR 6226 CPM, University of Rennes 1, 35042 Rennes, France Pers. address: 8 allée de Penmarch, 35700 Rennes, France

DOI:

https://doi.org/10.1007/966

Ключевые слова:

organylsilylfuryl(thienyl)nitrones, organylsilylfuryl(thienyl)nitroethenes, IR spectroscopy, 1H, 13C, 29Si NMR spectroscopy, electrochemical redox potentials, synthesis

Аннотация

Two series of potentially biologically active heteroaryl derivatives of nitrones and nitroethenes have been prepared and studied by cyclic voltammetry and DFT modeling. Satisfactory correlations of experimental first peak potentials Ep, both in oxidation and in
reduction, with the energies of the corresponding frontier orbitals were found.

How to Cite
Boulkroune, M.; Ignatovich, L.; Muravenko, V.; Spura, J.; Chibani, A.; Jouikov, V. Chem. Heterocycl. Compd. 2014, 49, 1579. [Khim. Geterotsikl. Soedin. 2013, 1706.]

For this article in the English edition see DOI 10.1007/s10593-014-1409-3

Биографии авторов

M. Boulkroune, Department of Chemistry, University Mentouri, 25000 Constantine, Algeria Pers. address: 122 Rue Kaddour Boumedous Bt D, Ciloc, Constantine, Algérie.

Mina Boulkroune

L. Ignatovich, Laboratory of Metalloorganic Chemistry Latvian Institute of Organic Synthesis

Luba Ignatovich

V. Muravenko, Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis

Velta Muravenko

J. Spura, Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis

Jana Spura

A. Chibani, Latvian Institute of Organic Synthesis

Head of the Laboratory of Metalloorganic Chemistry

V. Jouikov, UMR 6226 CPM, University of Rennes 1, 35042 Rennes, France Pers. address: 8 allée de Penmarch, 35700 Rennes, France

Viatcheslav Jouikov

Загрузки

Опубликован

2013-10-22

Выпуск

№ 11 (2013)

Раздел

Оригинальные статьи