Oxidative reactions of azines. 1. Ketohydroxylation of 4-Phenyl-1,2,5,6-tetrahydropyrines. Synthesis and structure of 3,4-dihydroxy-4-phenylpiperidin-2-ones and their acetoxy derivatives

Authors

  • A. T. Солдатенков Russian University of National Friendship, Moscow 117198
  • И. А. Бекро Russian University of National Friendship, Moscow 117198
  • Ж. А. Мамырбекова Russian University of National Friendship, Moscow 117198
  • C. А. Солдатова Russian University of National Friendship, Moscow 117198
  • А. Темесген Russian University of National Friendship, Moscow 117198
  • Н. Д. Сергеева Russian University of National Friendship, Moscow 117198
  • Л. Н. Кулешова Russian University of National Friendship, Moscow 117198
  • B. H. Хрусталев Russian University of National Friendship, Moscow 117198

Abstract

N-Alkyl substituted 4 phenyl-1,2,5,6-tetrahydropyridines which do not undergo Wagner hydroxylation are converted in good yields to the corresponding 3,4-dihydroxy-2-oxopiperidines under modified conditions for this reaction. The molecular structures of a 3,4-dihydroxy-4-phenylpiperidin-2-one and its diacetatate have been studied by X-ray crystalographic analysis.

How to Cite
Soldatenkov, A. T.; Bekro, I. A.; Mamyrbekova, Zh. A.; Soldatova, S. A.; Temesgen, A.; Sergeeva, N. D.; Kuleshova, L. N.; Khrustalev, V. N.  Chem. Heterocycl. Compd. 1996, 32, 197. [Khim. Geterotsikl. Soedin. 1996, 222.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01165446

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Published

1996-02-25

Issue

No. 2 (1996)

Section

Original Papers