SYNTHESIS OF DIASTEREOMERIC SPIROCYCLIC NITROXYL RADICALS OF 3-IMIDAZOLINE SERIES WITH TWO MESOGENIC GROUPS

Authors

  • Е. В. Зайцева N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
  • А. В. Шернюков N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
  • С. А. Амитина N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Р. Тамура Graduate School of Human and Environmental Studies, University of Kyoto
  • И. А. Григорьев N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Д. Г. Мажукин N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

DOI:

https://doi.org/10.1007/1692

Keywords:

4-hydroxycyclohexanone, 3-imidazolines, spirocyclic nitroxyl radicals, condensation, Mitsunobu acylation

Abstract

Alkylaromatic α-hydroxylamino ketones with a p-hydroxy(alkoxy)aryl substituent were used for the preparation of stable diastereomeric spirocyclic nitroxyl radicals of 3-imidazoline series, having two different or identical mesogenic groups in the molecule. The molecular structure of these compounds was determined by NMR study of their diamagnetic reduced derivatives.

How to Cite
Zaitseva, E. V.; Shernyukov, A. V.; Amitina, S. A.; Tamura, R.; Grigor'ev, I. A.; Mazhukin, D. G. Chem. Heterocycl. Compd. 2014, 50, 1113. [Khim. Geterotsikl. Soedin. 2014, 1207.]

For this article in the English edition see DOI 10.1007/s10593-014-1571-7

Author Biography

Е. В. Зайцева, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences

Елена Васильевна Зайцева

младший научный сотрудник

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Published

2014-09-08

Issue

No. 8 (2014)

Section

Original Papers